Coal resources have been used to produce liquid transportation fuels by several process routes, collectively referred to as coal liquefaction or, more generally stated, as Coal to Liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
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Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
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Coal liquefaction is the "coal to liquids" process that takes two steps (coal gasification and gas to liquids) to "upgrade" coal to synthetic liquid fuels, such as synthetic diesel and synthetic gasoline. Coal liquefaction has been a proven technology used for over 100 years and is undergoing a renaissance by a number of companies that believe ...
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The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FTIR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible ...
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Coal liquefaction process employing fuel from a combined gasifier. Patent Schmid, B. Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to ...
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New study shows liquefied natural gas might be worse for climate change than coal The findings have major implications for global climate goals and for the United States, which became the world ...
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The different liquefaction mechanisms of lignite including free radical, oxidation, alkanolysis, and hydrogenation lead to the corresponding products: preasphaltene and asphaltene, mixed carboxylic acids, mixed esters and ethers, and cyclic compounds, respectively.
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4. Coal Liquefaction Coal liquefaction is the conversion of coal into a synthetic oil in order to supplement natural sources of petroleum. It is an attractive technology because 1) It is well developed and thus could be implemented fairly rapidly and 2) There are relatively large quantities of coal reserves. 5.
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On the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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A coal liquefaction pilot plant of the NEDOL process, supported by the New Energy and Industrial Technology Development Organization (NEDO), was in successful operation for a total of 269 days at Kashima, Japan. The liquefaction section consisted of three reactors, 1 m in diameter, connected in series, and processed 150 tons of coal per day.
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This process is the only coal liquefaction scheme currently in use on a relatively large commercial scale; South Africa is currently using the Fischer−Tropsch process on a commercial scale in their complex. Thus, coal is converted to gaseous products at temperatures in excess of 800°C (1470°F), and at moderate pressures, to produce ...
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The article contains sections titled: 1. Introduction Commercial Development Historical Background 2. Indirect Coal Liquefaction Preparation of Synthesis Gas Co...
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Gasification While the goal of combustion is to produce the maximum amount of heat possible by oxidizing all the combustible material, the goal of gasification is to convert most of the combustible solids into combustible gases such as carbon monoxide, hydrogen, and methane. Gasification reactions
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Highlights. Coal liquefaction, the conversion of coal to a cleanburning, lowsulfurcontent fuel, is a technology that can augment petroleumderived products such as gasoline and boiler fuels and help meet the requirement for large supplies of liquid fuel. Direct liquefaction produces liquids through the interaction of coal and hydrogen at ...
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Investigation of the nonintegrated twostage coal liquefaction (NTSL) process was initiated at the Wilsonville Advanced Coal Liquefaction R and D Facility during May 1981 when the HOil hydrotreating unit came successfully online. The primary objective of this investigation is the development of a commercially feasible method of efficient ...
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the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
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The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significance for improving the oil yield of the direct liquefaction process and reducing the amount of pollution emitted from this oilcontaining organic solid waste. In ...
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Indirect liquefaction of coal (ICL) has been found to be the most commercially viable process involving the gasification of coal. ICL includes two steps; in the first step, coal is converted into syngas ( Coal+H2OCO+H2), and during the last step, syngas is synthesized in the presence of a catalyst into liquid fuels.
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The aim of this study is to investigate the transformation of hydrogendonor solvent tetralin in the direct liquefaction process of coal. Pure tetralin liquid as well as mixture of tetralin and Wucaiwan coal (WCW) were separately reacted under a liquefaction condition, and constituents of liquid product were analyzed by GCMS. The results show that after the tetralin liquid reacts with high ...
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3. Features of NEDOL Process˜ The NEDOL Process is a coal liquefaction process developed exclusively in Japan. The process has integrated the advantages of three bituminous liquefaction processes (Direct Hydrogenation Process, Solvent Extraction Process, and Solvolysis Process), thus providing superiority in both technology and economics. The
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Study on fluidized bed pyrolysis process of coal liquefaction residue and analysis of carbon emission reduction. March 2023; ... Fluidized bed pyrolysis and coke combustion process flow chart.
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Indirect liquefaction process coal is liquefied through the FischerTropsch (FTS) process. ... Coal liquefaction is favoured by the simple skeletal structure that comprises mainly of simple aromatic rings which are less likely to be removed from the lignin basing on the building block for phenyl propane (Durie 1982).
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What is coal liquefaction? Also called Coal to Liquid (CTL) technology, it is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2). The synthetic gas can be liquefied to its fuel ...
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When considering the development of coal liquefaction process using syngas, in addition to the above typical processes, hydrothermal liquefaction process is a technology worthy of reference. Hydrothermal liquefaction [110], [111], [112] is an effective and emerging technology that can convert both coals and biomass containing high moisture ...
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Fig. 12 shows the total costs of the whole coal liquefaction process together with the costs of four major parts: coal price, (coal) transportation, DCL production and distribution. Among three, "DCL_R" is the most economical one, the price of which is only two third of "DCL_H". For "DCL_H" and "DCL_R", the price caused by the ...
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Indirect liquefaction processes require first gasifying the solid feedstocks into a syngas. Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of ...
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History. In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. High prices of oil and natural gas led to increased interest in "BTU Conversion" technologies such as gasification, methanation and liquefaction. The Synthetic Fuels Corporation was a governmentfunded corporation established in 1980 to create a market ...
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Liquefaction. Coal liquefaction is a process of converting coal into liquid fuels or petrochemicals. There are several processes to accomplish this task. The two most common are the indirect route and the direct route [58, 59].
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid ...
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An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogenrich gases at ...
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An improved coal liquefaction process is provided which enables conversion of a coaloil slurry to a synthetic crude refinable to produce larger yields of gasoline and diesel oil. The process is characterized by a twostep operation applied to the slurry prior to catalytic desulfurization and hydrogenation in which the slurry undergoes partial ...
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An integrated coal pretreatment, liquefaction and gasification process is provided in which particulate coal is contacted with a vapor phase hydrogen donor solvent to swell the coal particles. The swollen coal particles are subjected to coal liquefaction conditions at relatively low temperatures.
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A process for twostage catalytic hydrogenation and liquefaction of coal to produce increased yields of lowboiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a processderived liquid solvent and fed at temperature below about
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misc{etde_609560, title = {Effect of catalyst addition on coliquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process ni okeru shokubai tenka koka} author = {Yokura, H, Nonaka, H, Matsumura, Y, Tsutsumi, A, and Yoshida, K} abstractNote = {Mixture of coal and cellulose was liquefied in supercritical water (400degC, 25 MPa ...
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article{osti_, title = {Catalyst withdrawal and addition in a coal liquefaction process}, author = {Simone, A A and Ogren, D F}, abstractNote = {The catalyst is withdrawn from a coal hydroliquefaction reactor while it is maintained on stream by withdrawing a portion of the catalyst, in a separate stream, dispersed in product from the liquefaction zone, with such withdrawn stream being ...
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